کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
11001910 1353702 2018 38 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Molecular and detailed isotopic structures of petroleum: Kinetic Monte Carlo analysis of alkane cracking
ترجمه فارسی عنوان
ساختارهای ایزوتوپ مولکولی و دقیق نفت: تجزیه کینتیک مونت کارلو از ترک خوردگی آلکال
موضوعات مرتبط
مهندسی و علوم پایه علوم زمین و سیارات ژئوشیمی و پترولوژی
چکیده انگلیسی
The compositional and bulk isotopic signatures of hydrocarbon compounds are routinely characterized to constrain the origin of oils and natural gases in sedimentary basins. Recent developments in clumped isotope geochemistry have given rise to a suite of measurements that provide new information on the thermal history of low molecular weight hydrocarbon gases. However, to date no study has linked these compositional, bulk and clumped isotope constraints to any mechanistic understanding of how these signatures develop and evolve. In this study, we developed a kinetic Monte Carlo method to predict consistent and simultaneous molecular distributions, bulk isotopic content, and detailed (multiply substituted and site-specific) isotopic structures of hydrocarbons from a cracking model. The detailed isotopic structure of the source (initially modeled as long alkanes), the intermediates, and the product molecules is followed as a function of the level of conversion due to cracking reactions. The bulk 13C content of gaseous alkane products generated via the model is shown to follow the linear natural gas plot at low conversion, but to deviate at high conversions. As examples of the information generated, the populations of center vs. terminal 13C-substituted propane are reported as a function of the starting alkane chain length and conversion and the population of doubly-13C-substituted ethane is described as a function of conversion and for different 13C substitution patterns in the source. The results are compared to experiment where possible and highlight the possibility of constraining hydrocarbon source isotopic structure and the nature of the generation processes leading to the formation of natural hydrocarbon deposits.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Geochimica et Cosmochimica Acta - Volume 243, 15 December 2018, Pages 169-185
نویسندگان
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