کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
11027051 | 1666328 | 2018 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synergistic crosslink of double bond and nitrile group of nitrile rubber in H2S environment
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
This study investigated the corrosion test of nitrile-butadiene rubber (NBR) in H2S. Butadiene rubber (BR) and hydrogenated nitrile-butadiene rubber (HNBR) were used to simulate the structural units of 1,4-polybutadiene and polyacrylonitrile in NBR. The characterizations of infrared spectra, CHNS elemental analysis, and XPS may indicate that when double bonds and nitrile groups coexist, NBR has the highest reactivity with H2S and crosslinks of monosulfur and disulfide appear inside the rubber. However, the reactivity of BR and HNBR was reduced and no crosslinking was produced when both were isolated. Therefore, double bonds and nitrile groups have a synergistic effect in the H2S environment.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Degradation and Stability - Volume 157, November 2018, Pages 108-118
Journal: Polymer Degradation and Stability - Volume 157, November 2018, Pages 108-118
نویسندگان
Chuanbo Cong, Qingkun Liu, Jia Li, Xiaoyu Meng, Qiong Zhou,