کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1230781 1495199 2017 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Design, properties and application of a facile fluorescence switch for Cu(II)
ترجمه فارسی عنوان
طراحی، خواص و به کارگیری یک سوئیچ فلورسانس آسان برای مس (II)
کلمات کلیدی
پروب فلورسانس؛ شیف باز؛ یونهای فلزی؛ در نمونه های آب؛ فعال- غیرفعال
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
چکیده انگلیسی


• A facile fluorescence switch with Schiff base units was designed and synthesized.
• The probe has a fluorescence “turn-on” signal for Cu(II) ions.
• The probe shows high selectivity and sensitivity for Cu(II) ions.
• The probe can be used to detect Cu(II) ions in practical samples.

A facile fluorescence switch based on Schiff base 2,2′-[1,3-phenylenbis- (methylidynenitrilo)]bis[benzenethiol] (PMBB) has been developed and used to sensing metal ions. UV–vis absorption and fluorescence emission spectra show that the PMBB receptor has high selectivity and sensitivity for Cu(II) ions. Based on the photoinduced electron transfer (PET) and chelation enhanced fluorescence (CHEF) mechanisms, the receptor exhibits an fluorescence “turn-on” switch signal for Cu(II). The 1:1 binding mode of PMBB and Cu (II) ions can be obtained by the Job-plot and ESI-Mass spectra data. Noticeably, the color changes (from colorless to yellow) of PMBB solutions for Cu(II) sensing can be observed by naked eyes in the sunlight. The detection limit of the receptor for Cu(II) may reach 10− 7 mol/L with a good linear relation in the lower concentrations of Cu(II). To develop the practical application, the Cu(II) ions in swimming pool water samples were detected. Results show that PMBB receptor as a fluorescent probe can use to detect the trace level of Cu(II) in the environmental samples. This work contributes to providing a facile strategy for designing efficient probes and developing their practical application value.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 170, 5 January 2017, Pages 65–68
نویسندگان
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