Study of antibacterial activity of Ag and Ag2CO3 nanoparticles stabilized over montmorillonite

• The synthesis of Ag-NPs in presence of Na2CO3 and ethylene glycol over MMT.
• Ag2CO3-MMT was prepared in presence of Na2CO3 and water as solvent.
• Diameter of Ag nanoparticles is increased in absence of Na2CO3.
• Ethylene glycol is used as reducing agent and montmorillonite is a stabilizer.
• Antibacterial activity of Ag-MMT is less than Ag2CO3-MMT.

Silver carbonate and silver nanoparticles (NPs) over of stabilizer montmorillonite (MMT) have been synthesized in aqueous and polyol solvent, respectively. Dispersions of silver nanoparticles have been prepared by the reduction of silver nitrate over of MMT in presence and absence of Na2CO3 compound in ethylene glycol. It was observed that montmorillonite was capable of stabilizing formed Ag nanoparticles through the reduction of Ag+ ions in ethylene glycol. Na2CO3 was used as carbonate source in synthesis of Ag2CO3 NPs in water solvent and also for controlling of Ag nanoparticles size in ethylene glycol medium. The samples were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), and ultraviolet–visible diffuse reflectance spectroscopy (DRS). The TEM images showed that Ag NPs size in presence Na2CO3 salts was smaller than without that. The results indicated intercalation of Ag and Ag2CO3 nanoparticles into the montmorillonite clay layers. The diffuse reflectance spectra exhibited a strong surface plasmon resonance (SPR) adsorption peak in the visible region, resulting from Ag nanoparticles. The antibacterial testing results showed that the Ag2CO3-MMT nanocomposite exhibited an antibacterial activity higher than Ag-MMT sample against Escherichia coli.

Figure optionsDownload as PowerPoint slide