Measurements of stress and fracture in germanium electrodes of lithium-ion batteries during electrochemical lithiation and delithiation

• Stresses were measured in-situ in a-LixGe during electrochemical cycling.
• a-LixGe was found to flow plastically at significantly lower stresses than a-LixSi.
• The elastic modulus was measured in a-LixGe as a function of lithium concentration.
• The fracture energy of a-LixGe was measured, indicating a brittle material.
• a-LixGe exhibits an unusual combination of plastic flow and brittle fracture.

We measure stresses that develop in sputter-deposited amorphous Ge thin films during electrochemical lithiation and delithiation. Amorphous LixGe electrodes are found to flow plastically at stresses that are significantly smaller than those of their amorphous LixSi counterparts. The stress measurements allow for quantification of the elastic modulus of amorphous LixGe as a function of lithium concentration, indicating a much-reduced stiffness compared to pure Ge. Additionally, we observe that thinner films of Ge survive a cycle of lithiation and delithiation, whereas thicker films fracture. By monitoring the critical conditions for crack formation, the fracture energy is calculated using an analysis from fracture mechanics. The fracture energies are determined to be Γ = 8.0 J m−2 for a-Li0.3Ge and Γ = 5.6 J m−2 for a-Li1.6Ge. These values are similar to the fracture energy of pure Ge and are typical for brittle fracture. Despite being brittle, the ability of amorphous LixGe to flow at relatively small stresses during lithiation results in an enhanced ability of Ge electrodes to endure electrochemical cycling without fracture.

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