کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1313515 | 1499312 | 2016 | 5 صفحه PDF | دانلود رایگان |
• Stereoselective and quantitative [2 + 2] photodimerization.
• Solid-state synthesis of fluoroarene.
• Polyfluorophenyl interactions.
The symmetrical octafluoro stilbene trans-1,2-bis(2,3,5,6-tetrafluorophenyl)ethylene (1) undergoes a stereoselective and quantitative [2 + 2] photodimerization in the solid state. The olefin self-assembles via C-H⋯F and face-to-face interactions of the fluorinated phenyl rings into a geometry for a topochemical photodimerization. The crystal structure and stereochemistry of the photoproduct rctt-1,2,3,4-tetrakis(2,3,5,6-tetrafluorophenyl)cyclobutane (2) has been determined.
The symmetrical octafluoro stilbene undergoes a stereoselective and quantitative [2 + 2] photodimerization in the solid state. CH⋯F interactions and face-to-face stacking dominate the self-assembly of the alkene in the solid. The resulting cyclobutane possesses four polyfluoro phenyl groups in a rctt-configuration.Figure optionsDownload as PowerPoint slide
Journal: Journal of Fluorine Chemistry - Volume 188, August 2016, Pages 5–9