کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1322006 1499850 2015 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrophilic C–H activation of benzene with a Shilov-inspired rhodium(III) diimine complex
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Electrophilic C–H activation of benzene with a Shilov-inspired rhodium(III) diimine complex
چکیده انگلیسی


• The complex [Rh(diimine) (CH3) (H2O)3]2+ has been synthesized and characterized.
• The complexes are octahedral and water soluble.
• X-ray structures have been obtained for all complexes.
• [Rh(diimine) (CH3) (H2O)3]2+ can catalyze H/D exchange between benzene and CF3CO2D.

Four new air and water stable, organometallic rhodium(III) complexes trans-RhIII(α-diimine) (CO)I2Me, 1, [RhIII(α-diimine) (C(O)Me) (H2O)3][BF4]2, 2, [RhIII(α-diimine)Me(H2O)3] [BF4]2, 3, and RhIII(α-diimine) (C(O)Me) (H2O) (OC(O)CF3)2, 4 (α-diimine = 1,4-bis(Ar)-2,3-dimethyl-1,4-diaza-1,3-butadiene, Ar = 3,5-dimethylphenyl) were synthesized and characterized by X-ray crystallography. H/D exchange of C6H6 with TFA-d1 (TFA = trifluoroacetic acid) was observed with 4 mol% loading of 3 at 100 °C with 137 turnovers (98% completion at 91% deuterium incorporation) in 24 h. 3 showed sustained catalytic activity towards H/D exchange of benzene even after three iterations of catalyst recycling.

This article describes the synthesis and characterization of the complex [Rh(diimine) (CH3) (H2O)3]2+. The complex is octahedral and water soluble, and can catalyze H/D exchange between benzene and CF3CO2D.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 793, 15 September 2015, Pages 192–199
نویسندگان
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