کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1335025 | 1500224 | 2016 | 8 صفحه PDF | دانلود رایگان |
The molecular structure of the nickel formate compound, Ni(py)4(O2CH)2·2py, has been determined by X-ray diffraction, thereby demonstrating that the formate ligand coordinates in a unidentate manner. A similar investigation of the nitrate compound, Ni(py)4(ONO2)2·2py, indicates that the nitrate ligand also coordinates in a unidentate manner; however, the Ni–O–NO2 bond angle is distinctly bent, in contrast to the linear geometry that was previously reported.
The molecular structures of the nickel formate and nitrate compounds, Ni(py)4(O2CH)2·2py and Ni(py)4(ONO2)2·2py, have been determined by X-ray diffraction, thereby demonstrating that both ligands coordinate in a unidentate manner. Of note, the Ni–O–NO2 bond angle is distinctly bent, in contrast to the linear geometry that was previously reported.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 116, 25 September 2016, Pages 189–196