کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1400969 1501692 2016 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Encapsulation of one-dimensional cation chains into pseudo-channels by varying monomers with opposite charge
ترجمه فارسی عنوان
کپسوله سازی از زنجیره های کاتیون تک بعدی در داخل شبه کانال ها توسط منومرهای متغیر با بار مخالف
کلمات کلیدی
زنجیره های کاتیونی؛ آنیون مونومر؛ کپسوله سازی؛ تعامل پیوند H ؛ پلیمر هماهنگی
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
چکیده انگلیسی


• Two compounds with cation chains and anion monomers have been synthesized.
• In 1, the monomer anions stack to generate a 1D pseudo channels encapsulation of cationic chains.
• In compound 2, the one-dimensional cation chains locate in pseudo-channels by monomers anions.
• When considering the H-bonding interaction, two 3D architectures for these compounds are generated.

Two compounds with cation chains and monomers, [Co1/2(bpbenz)1/2]+·[Co1/2(oba)]− (1) and [Ni(DPT)(H2O)4]2+ [tpdc]2− (2) have been synthesized under hydrothermal condition (bpbenz = 1,4-bis(4-pyridyl)benzene, H2oba = 4,4′-oxybis- (benzoate), DPT = 2,5-dipyridinethiophene, H2tpdc = biphenyldicarboxylic acid). In compound 1, the monomer [Co1/2(oba)]− anions stack in three orientations to generate a 1D pseudo channels encapsulation of cationic chains [Co1/2(bpbenz)1/2]+. When considering the H-bonding interaction between coordinated water O atoms of the [Co1/2(bpbenz) 1/2]+ cationic chain and uncoordinated carboxylate oxygen atoms of the [Co1/2(oba)]− anion, a binodal 3,6-coordinated 3D architecture is generated. Like 1, the one-dimensional cation chains [Ni(DPT)(H2O)4]2+ locate in pseudo-channels by [tpdc]2− monomers anions in compound 2. A 3D net is also generated considering the H-bonding interaction.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 1125, 5 December 2016, Pages 546–549
نویسندگان
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