Synthesis, structural and optical properties of Eskolaite nanoparticles derived from Cr doped polyanthranilic acid (CrPANA)

• K2Cr2O7 has been used as an oxidant and a dopant of polyanthranilic acid.
• Cr doped polyanthranilic acid has been used as a precursor of Cr2O3 nanoparticles.
• Cr2O3 nanoparticles has been characterized by XRD and TEM.
• The optical band gap of Cr2O3 nanoparticles has been measured.

Cr doped polyanthranilic acid (Cr PANA) has been used as a molecular precursor of Cr2O3 nanoparticles. Potassium dichromate acted as an oxidant and a dopant in Cr PANA synthesis. The spectral, optical and thermal properties of the precursor have been described. Thermogravimetric Analysis (TGA) and differential scanning calorimetric (DSC) were used to clarify the thermal stability of Cr PANA. The optical band gap (Eg) measurements indicated that Cr PANA has wider optical band than the pure PANA. Calcination of Cr PANA at 600 °C produced Eskolaite (Cr2O3) nanoparticles. The obtained nanoparticles have been characterized by XRD and TEM. The average size of the nanoparticles was found to be 70 nm. The measured optical band gap of Eskolaite nanoparticles is 0.35 eV wider than the bulk.

XRD pattern of Cr2O3 nanoparticles derived from Cr PANA after calcination at 600 °C.Figure optionsDownload as PowerPoint slide