کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
146799 456378 2015 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Isomerization of 1-decene: Estimation of thermodynamic properties, equilibrium composition calculation and experimental validation using a Rh-BIPHEPHOS catalyst
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Isomerization of 1-decene: Estimation of thermodynamic properties, equilibrium composition calculation and experimental validation using a Rh-BIPHEPHOS catalyst
چکیده انگلیسی


• Calculation of thermodynamic properties of formation for all possible decene isomers.
• Application of Gibbs energy minimization to be independent of unknown stoichiometry.
• Determination of trans-2-decene as the thermodynamical most stable isomer.
• Isomerization kinetics are independent of the solvent polarity.
• Successful experimental validation of the calculation results.

The Rh-BIPHEPHOS catalyzed double bond isomerization of 1-decene as representative substrate for the hydroformylation of long-chain olefins was investigated. To obtain information about the thermodynamic equilibrium between the possible isomers of 1-decene, including all individual cis/trans isomers, calculations based on Gibbs energy minimization were performed and experimentally validated. The necessary thermodynamic properties of formation were calculated using Benson’s group increment theory (BGIT) method. Kinetic validation experiments were performed with 1-decene in two different solvents (DMF, toluene) to evaluate solvent polarity effects on the concentration courses. The experimentally determined equilibrium isomer composition was in very good agreement with the predictions. Thus, reaction isomerization equilibrium constants can be predicted reliably based on the applied method and can be used in subsequent kinetic investigations.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 260, 15 January 2015, Pages 513–523
نویسندگان
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