Non-metal doped TiO2 nanotube arrays for high efficiency photocatalytic decomposition of organic species in water

• The electrochemical doping strategy was proposed to fabricate non-metal doped TiO2NT.
• Non-metal doped TiO2 nanotubes generate higher photocurrents.
• The bandgap energy of all doped materials was decreased when compared to pure titania.

Titanium dioxide is a well-known photoactive semiconductor with a variety of possible applications. The procedure of pollutant degradation is mainly performed using TiO2 powder suspension. It can also be exploited an immobilized catalyst on a solid support. Morphology and chemical doping have a great influence on TiO2 activity under illumination. Here we compare photoactivity of titania nanotube arrays doped with non-metal atoms: nitrogen, iodine and boron applied for photodegradation of organic dye - methylene blue and terephtalic acid. The doped samples act as a much better photocatalyst in the degradation process of methylene blue and lead to the formation of much higher amount of hydroxyl radicals (
• OH) than undoped TiO2 nanotube arrays. The use of a catalyst active under solar light illumination in the form of thin films on a stable substrate can be scaled up for an industrial application.

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