Temperature-induced spin reorientation and magnetization jump of rare-earth orthoferrite Ho0.5Pr0.5FeO3 single crystal

• Ho0.5Pr0.5FeO3 single crystal was grown by optical floating zone method.
• It shows an abrupt jump of magnetization along a axis at low temperature.
• The jump height and temperature is sensitive to external applied magnetic field.
• It is attributed to the spin reversal of the rare earth ions.

We report temperature-induced spin reorientation and magnetization jump effects in the rare earth (RE) orthoferrite Ho0.5Pr0.5FeO3 single crystal. The single crystal of about 6 mm in diameter and 50 mm in length was successfully grown by optical floating zone method. Both X-ray diffraction and Laue photograph confirmed the homogeneity and high quality of the crystal. Magnetic properties of Ho0.5Pr0.5FeO3 single crystal are studied over a wide temperature range from 2 to 300 K. Spin reorientation transition from Γ2 to Γ4 phase is observed in the temperature range of 75–90 K. At lower temperature, the Ho0.5Pr0.5FeO3 shows an abrupt jump of magnetization along the a-axis, which occurs only in the field-cooling process, and is sensitive to external applied magnetic field. By analyzing the jump temperature and magnitude of the magnetization, we conclude that it is caused by the spin reversal of the rare earth ions. The isothermal magnetization versus field hysteresis loop measurements along a axis explain the spin configuration variation from 3 K to 60 K.