کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1799077 | 1524837 | 2015 | 6 صفحه PDF | دانلود رایگان |
• Effect of reduction of particle size on magnetocaloric properties of NdMnO3 has been investigated.
• The roles of Nd3+-ordering and self-doping effect on magnetic and magnetocaloric properties of NdMnO3 have been discussed.
• Nanocrystalline NdMnO3 exhibits large magnetocaloric effect (MCE) in two temperature regimes in contrary to bulk sample.
• We emphasize how MCE study can be exploited to explore fundamental physics of magnetism.
Magnetocaloric properties of NdMnO3 were investigated in its bulk polycrystalline and nanocrystalline forms. The nanocrystalline sample (average particle size ∼40 nm) exhibits a maximum in the temperature dependence of magnetic entropy change [−ΔSM(T)] at ∼70 K due to the paramagnetic to ferromagnetic transition, which is absent in case of its bulk counterpart. The absence of peak in −ΔSM(T) in the bulk sample is attributed to the co-existence of antiferromagnetic and ferromagnetic phases. A canted magnetic state (CMS) is stabilized at low temperature for both the samples due to the ordering of Nd3+ giving rise to a peak in −ΔSM(T) at ∼15 K. Interestingly −ΔSM(T) for these two samples show a universal behavior near their transitions at low temperature although their temperature dependence of magnetization is markedly different around those transitions. A detailed analysis of magnetocaloric data conclusively establishes the existence of a canted magnetic state, which is not obvious from magnetometry, demonstrating the usefulness of this method for probing phase coexistence and multiple magnetic states in complex oxide systems.
Journal: Journal of Magnetism and Magnetic Materials - Volume 384, 15 June 2015, Pages 138–143