کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
201089 | 460533 | 2016 | 5 صفحه PDF | دانلود رایگان |
• Determine the solubility of 4-chlorotoluene in subcritical water visually.
• Solubility of 4-chlorotoluene increases linearly from 262 to 294 °C.
• Obtained Raman spectra of water during the dissolution process of 4-chlorotoulene.
The solubility of 4-chlorotoluene in subcritical water was measured using an optically transparent fused silica capillary reactor (FSCR). The total dissolution temperature of 4-chlorotoluene in subcritical water was visually determined. The dissolution uniformity of 4-chlorotoluene in subcritical water was confirmed by Raman spectroscopy. The solubility of 4-chlorotoluene linearly increased with increasing temperature in the range 262.3–293.8 °C. The dissolution mechanism of 4-chlorotoluene in subcritical water is proposed based on the Raman spectra of 4-chlorotoluene and water during the dissolution process in the FSCR.
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Journal: Fluid Phase Equilibria - Volume 425, 15 October 2016, Pages 93–97