کد مقاله کد نشریه سال انتشار مقاله انگلیسی ترجمه فارسی نسخه تمام متن
4765710 1362360 2018 7 صفحه PDF ندارد دانلود رایگان
عنوان انگلیسی مقاله
Construction and optical properties of dithienylethene-based photoswitchable [n]rotaxane (n = 2, 3)
کلمات کلیدی
Dithienylethene; Rotaxane; Photoswitchable; Synthesis; Photochromism; Fluorescence;
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Construction and optical properties of dithienylethene-based photoswitchable [n]rotaxane (n = 2, 3)
چکیده انگلیسی

•Photoswitchable [n]rotaxanes based on dithienylethene unit were synthesized.•The photochromic properties and fluorescence behaviors were also investigated.•Non-covalent components could influence the photoswitching properties.•Photochromic signal (such as molar absorption coefficient) t can be integrated.

Mechanically interlocked structures such as rotaxanes and catenanes provide a novel backbone for constructing functional materials with unique structural characteristics. In this study, the novel photoswitchable [n]rotaxanes 11 and 12 based on dithienylethene unit were efficiently synthesized by the classical template-directed clipping approach. And their structures were well-confirmed by NMR, MS and elemental analysis. Investigation on photochromic properties indicated that dithienylethene-based [n]rotaxanes had good reversibility and excellent fatigue resistance upon irradiation with UV or visible light. And they displayed also excellent fluorescence switchable behavior. Interestingly, It was found that [2]rotaxane 11 had better photoisomerization properties in comparison to its corresponding macrocycle 4, which indicated that the non-covalent components on the [2]rotaxane 11 could influence the photoswitching properties. Furthermore, the mechanically interlocked molecules containing two dithienylethene backbones displayed around a 2-fold increase in the molar absorption coefficient compared with that of the mono dithienylethene derivative, which was consistent with the reported [n]rotaxane 9 and 10.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 148, January 2018, Pages 130-136
نویسندگان
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