کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4768260 | 1424952 | 2018 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Biodiesel production from soybean oil and dimethyl carbonate catalyzed by potassium methoxide
ترجمه فارسی عنوان
تولید بیودیزل از روغن سویا و دی متیل کربنات کاتالیز شده با متاکسید پتاسیم
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کلمات کلیدی
تبادل استری؛ تبلور مجدد. متانول؛ متیل استر اسید چرب
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
A study of the soybean oil transesterification reaction with dimethyl carbonate (DMC) catalyzed by potassium methoxide prepared through recrystallization process in presence of methanol was done. Reaction variables were analyzed viz. temperature of 40, 60 and 80â¯Â°C, DMC to oil molar ratio of 2:1, 4:1, 6:1, 8:1 and 10:1, and catalyst concentration of 1, 1.5 and 2â¯wt% in relation to oil, aiming to obtain the best condition for reaction. Triglyceride conversion of 99% was achieved for 6:1 DMC:oil molar ratio, 2.0â¯wt% of catalyst concentration and 80â¯Â°C after 15â¯min of reaction. Experiments were carried out to investigate methanol effects in DMC/oil medium and also to compare reactions with recrystallized and heterogeneous catalysts. Potassium methoxide recrystallized in presence of methanol achieved a triglyceride (TG) conversion higher than 99% while only a 20% TG conversion was achieved from heterogeneous reaction at same condition. Potassium quantification in biodiesel phase was done in order to investigate the homogeneous pathway catalysis in recrystallized catalyst reaction.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 212, 15 January 2018, Pages 101-107
Journal: Fuel - Volume 212, 15 January 2018, Pages 101-107
نویسندگان
Dian Celante, João VÃtor Diel Schenkel, Fernanda de Castilhos,