کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4907558 | 1426572 | 2017 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Adsorption and corrosion inhibition properties of 5-amino 1,3,4-thiadiazole-2-thiol on the mild steel in hydrochloric acid medium: Thermodynamic, surface and electrochemical studies
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The inhibition effect of 5-amino 1,3,4-thiadiazole-2-thiol (5-ATT) on the corrosion of mild steel in 1 M HCl solution at 303 K was studied practicing weight loss, electrochemical electrochemical (AC and DC) studies and X-ray photoelectron spectroscopy (XPS) methods. The obtained results showed that 5-ATT was an effective inhibitor in HCl medium. The inhibition efficiency, η(%), increased with the increase in concentration inhibitor but the temperature has almost no effect on the inhibition efficiency of 5-ATT. The activation dissolution thermodynamic parameters were calculated and discussed. Thermodynamic data and XPS analysis clearly show that the adsorption mechanism of 5-ATT on the mild steel surface in 1 M HCl solution is mainly electrostatic-adsorption. Tafel curves reveal that 5-ATT behaves as a mixed-type inhibitor with cathodic predominance and obeyed Langmuir adsorption isotherm. With the aim of extracting the parameters of the electrochemical impedance spectroscopy an appropriate equivalent circuit model was offered.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 803, 15 October 2017, Pages 125-134
Journal: Journal of Electroanalytical Chemistry - Volume 803, 15 October 2017, Pages 125-134
نویسندگان
H. Ouici, M. Tourabi, O. Benali, C. Selles, C. Jama, A. Zarrouk, F. Bentiss,