Thermal performance of calcium-rich alkali-activated materials: A microstructural and mechanical study

The effects of Si/Al, Na/Al and water/solids ratios on thermal performance of alkali-activated materials (AAM) based on fly ash-slag blends are investigated. Higher Na/Al decreased compressive strength but increased post-heated strength retention and mass loss while reducing cracking at 1000 °C. Lower Si/Al resulted in lowest initial strength but highest thermal stability, with an increase in strength after exposure to 1000 °C, while a high degree of cracking was observed at higher Si/Al ratio. The effect of w/s on thermal performance was subtle. Computed tomography analysis showed for the first time thermally induced expansion of pores which reduced surface cracking via water vapour pressure release. Thermal performance of alkali-activated materials (AAM) is significantly better than Portland cement (PC) of the same compressive strength because of the very low bound water content. The porosity, pore connectivity and number of pores of the AAM were considerably higher than those in the PC binder.