|کد مقاله||کد نشریه||سال انتشار||مقاله انگلیسی||ترجمه فارسی||نسخه تمام متن|
|49214||46724||2016||3 صفحه PDF||ندارد||دانلود رایگان|
• Sodium salt of 4,5-dicarboxyphthalocyanine of cobalt is used as a catalyst for Fischer-Tropsch synthesis
• Addition of perfluorodecaline to the reaction mixture resulted in a dramatic increase of the yield of liquid products.
• The slurry Fischer-Tropsch process can be improved using mixed solvents containing ionic liquids and fluorinated solvents.
The activity of a sodium salt of 4,5-dicarboxyphthalocyanine of cobalt has been studied in Fischer–Tropsch synthesis in a slurry mode (autoclave) using ionic liquids and a mixture of the ionic liquid with perfluorodecaline as solvents. The addition of perfluorodecaline to the reaction mixture resulted in a dramatic increase of the yield of liquid products.
Graphical abstractFischer–Tropsch synthesis by Co-phthalocyanine complex in ionic liquids and a mixture of BMIM-BF4 and perfluorodecaline (280 °C, 30 atm).Figure optionsDownload full-size imageDownload as PowerPoint slide
Journal: Catalysis Communications - Volume 75, 5 February 2016, Pages 42–44