|کد مقاله||کد نشریه||سال انتشار||مقاله انگلیسی||ترجمه فارسی||نسخه تمام متن|
|49248||46730||2016||3 صفحه PDF||ندارد||دانلود رایگان|
• We first used G-triplex–Cu2 + as an enantioselective catalyst.
• Diels–Alder reaction could be catalyzed by our complex.
• We measured the reaction kinetics.
• The substrate specifity was well studied.
In this study, it was found that the G-triplex DNA could be used as an enantioselective catalyst without further addition of ligands in Diels–Alder reactions when coordinated with copper ions, for the first time. The efficiency and selectivity of the catalyst were investigated. The kinetic measurements were made using ultraviolet (UV) light. The stability of the catalyst in aqueous buffer was confirmed by circular dichroism (CD) and nuclear magnetic resonance (NMR) spectra.
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Journal: Catalysis Communications - Volume 74, 10 January 2016, Pages 16–18