کد مقاله کد نشریه سال انتشار مقاله انگلیسی ترجمه فارسی نسخه تمام متن
49398 46741 2016 4 صفحه PDF ندارد دانلود رایگان
عنوان انگلیسی مقاله
An effective and stable Ni2P/TiO2 catalyst for the hydrogenation of dimethyl oxalate to methyl glycolate
ترجمه فارسی عنوان
کاتالیست Ni2P / TiO2 موثر و پایدار برای هیدروژنه شدن دی متیل اکسالات به متیل گلیکولات
کلمات کلیدی
دی متیل اگزالات؛ متیل گلیکولات؛ هیدروژن؛ Ni2P
Dimethyl oxalate; Methyl glycolate; Hydrogenation; Ni2P
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
چکیده انگلیسی


• An effective Ni2P/TiO2 catalyst was proposed for dimethyl oxalate hydrogenation.
• A 93.0% conversion of dimethyl oxalate was obtained under 210 °C.
• A selectivity of 88.0% to methyl glycolate was achieved under 210 °C.
• Ni2P/TiO2 catalyst showed a superior stability which can be performed for 3600 h.

An effective and stable bifunctional Ni2P/TiO2 catalyst was proposed for gas-phase hydrogenation of dimethyl oxalate to corresponding alcohols. A 93.0% conversion of DMO with a selectivity of 88.0% to methyl glycolate was observed under 210 °C. Moreover, the catalyst showed an excellent stability which can be performed for 3600 h under the reaction conditions of 230 °C, 3 MPa H2 and the weight space velocity of 0.1 h− 1.

Graphical abstractAn effective and stable Ni2P/TiO2 catalyst for the hydrogenation of dimethyl oxalate to methyl glycolate with an excellent stability (3600 h) was proposed.Figure optionsDownload full-size imageDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 73, 5 January 2016, Pages 46–49
نویسندگان
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