کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4979825 | 1453036 | 2017 | 22 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Simultaneous and continuous stabilization of As and Pb in contaminated solution and soil by a ferrihydrite-gypsum sorbent
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
For the increasing need of stabilization both cationic and anionic metal(loid)s simultaneously, we newly developed a metal sorbent (FIXALL), consisting mainly of ferrihydrite and gypsum. The objectives of this study were to determine the molecular mechanisms of Pb and As stabilization in an aqueous system and to examine a simultaneous and long-term (up to 754 days) effect on Pb and As stabilization in an anthropogenically contaminated soil using the FIXALL sorbent. When the solution contained a low concentration of Pb (5 mg Lâ1), the mechanisms of Pb removal by FIXALL were based chiefly on the formation of inner-sphere surface complex with ferrihydrite. In the highly concentrated Pb solution (1200 mg Lâ1), contrarily, the removal of Pb by FIXALL was the direct consequence of the dissolution of gypsum and subsequent precipitation of PbSO4, which strengthens the drawback of low capability of ferrihydrite for Pb removal. Regardless of initial concentrations, the primary mechanism of FIXALL for As stabilization is attributed to the formation of inner-sphere surface complex with ferrihydrite. A contaminated soil study demonstrated that FIXALL could decrease the concentration of water soluble As and Pb simultaneously and continuously for 754 days without notable changes in their chemical species and soil pH.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 327, 5 April 2017, Pages 171-179
Journal: Journal of Hazardous Materials - Volume 327, 5 April 2017, Pages 171-179
نویسندگان
Kentaro Kameda, Yohey Hashimoto, Shan-Li Wang, Yasumasa Hirai, Hidetaka Miyahara,