کد مقاله کد نشریه سال انتشار مقاله انگلیسی ترجمه فارسی نسخه تمام متن
49809 46768 2016 5 صفحه PDF ندارد دانلود رایگان
عنوان انگلیسی مقاله
Hydrogen generation at ambient conditions: AgPd bimetal supported on metal–organic framework derived porous carbon as an efficient synergistic catalyst
ترجمه فارسی عنوان
تولید هیدروژن در شرایط محیطی: دوقلوهای AgPd بر روی چارچوب فلزات و الیاف کربن متخلخل متصل شده به عنوان یک کاتالیزور کارآمد ترکیب کننده
کلمات کلیدی
چیدمان آلومینیوم متشکل از کربن متخلخل دوقلو AgPd؛ اسید فرمیک؛ Dehydrogenation
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
چکیده انگلیسی


• Ag–Pd bimetal supported on the MOF-5 derived nanoporous carbon was fabricated.
• The catalyst exhibited excellent catalytic activity for the dehydrogenation of FA.
• The initial turnover frequency was 854 h− 1.

An efficient synergistic catalyst, AgPd bimetal supported on metal–organic framework derived porous carbon (AgPd/MOF-5-C), was fabricated for the first time. The catalyst exhibited 100% H2 selectivity and high catalytic activity in hydrogen generation from formic acid at ambient conditions. The initial turnover frequency could reach as high as 854 h− 1. The combination of distinct interaction among bimetal, support and high dispersion of nanoparticles drastically enhances the catalytic performance of the resulted catalyst.

Graphical abstractAn efficient synergistic catalyst, AgPd bimetal supported on metal–organic framework derived porous carbon (AgPd/MOF-5-C), was fabricated for the first time. The catalyst exhibited 100% H2 selectivity and high catalytic activity in hydrogen generation from formic acid. At ambient conditions, the initial turnover frequency could reach as high as 854 h− 1.Figure optionsDownload full-size imageDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 78, 10 March 2016, Pages 17–21
نویسندگان
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