کد مقاله کد نشریه سال انتشار مقاله انگلیسی ترجمه فارسی نسخه تمام متن
4988596 1368068 2018 9 صفحه PDF ندارد دانلود رایگان
عنوان انگلیسی مقاله
Tuning the ion channel network of perfluorosulfonated membranes via a facile sacrificial porogen approach
کلمات کلیدی
Sacrificial porogen; Sulfonated polystyrene; Membrane morphology; SAXS/WAXS; Perfluorosulfonated membranes;
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
Tuning the ion channel network of perfluorosulfonated membranes via a facile sacrificial porogen approach
چکیده انگلیسی

•Tailored pore sizes and transport properties via water-soluble porogen approach.•Increased ion channel interconnectivity for porogen contents below 30%.•Enlargement of the ion channel sizes at porogen contents equal to or above 30%.

The morphology in terms of the ion channel size, apparent porosity and tortuosity of perfluorosulfonated membranes was modified by using sulfonated polystyrene (SPS) as a sacrificial porogen. The precursor polymers were fabricated via solution-casting of the commercially available Nafion solution together with SPS. Upon swelling SPS was leached from the membrane matrix resulting in the formation of larger nanosized ion channels and clusters and hence a more open membrane matrix in fully hydrated conditions. Below a threshold value of 30% SPS, the membranes maintained high permselectivity and the porogen mainly increased the apparent porosity and network interconnectivity resulting in increased hydraulic permeability, streaming potential coefficient and membrane conductivity. Higher porogen contents resulted in larger characteristic hydrophilic domain sizes, quantified from SAXS/WAXS, and enhanced membrane conductivity up to 300% with only a slight decrease in the permselectivity in dilute LiCl solutions. These results together confirm the effective modification of the charged nanoscopic ion network and clearly indicate that SPS can efficiently be used for precise tuning the PTFE-based membrane matrix to achieve tailored transport properties for specific electrochemical applications.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 545, 1 January 2018, Pages 275-283
نویسندگان
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