کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4989869 | 1456934 | 2017 | 9 صفحه PDF | دانلود رایگان |
- NiO/TiO2 NTAs photoelectrode has been fabricated through electrodeposition process.
- NiO/TiO2 NTAs photoelectrode exhibited high PC performance for decomposition of 4-CP.
- The enhanced visible light PC mechanism was proposed.
In the study, we report that p-type NiO (p-NiO) nanoparticles were successfully decorated onto the surface of n-type TiO2 nano-tube arrays (n-TiO2 NTAs) photoelectrode by anodization process, followed by electrodeposition strategy in the presence of NiSO4 electrolyte. After then, the samples were studied by scanning electron microscope (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). In addition, the optical and photoelectrochemical (PECH) properties of p-NiO/n-TiO2 NTAs were recorded through ultraviolet-visible diffuse reflectance spectroscopy (UV-vis DRS), open circuit potential (OCP) and electrochemical impedance spectroscopy (EIS) curves, respectively. Furthermore, We evaluated the photocatalytic (PC) degradation of 4-chlorphenol and the enhanced PC mechanism was also discussed. Results suggest that p-NiO/n-TiO2 NTAs photoelectrode exhibited higher PC activities than that of pristine TiO2 NTAs owing to its higher photogeneration electrons-holes (e/h+) pairs separation efficiency and light absorbance. As a consequence, the p-NiO/n-TiO2 NTAs photoelectrode could be applied in degradation of organic pollutants and wastewater purification.
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Journal: Separation and Purification Technology - Volume 186, 2 October 2017, Pages 1-9