کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4990121 | 1456943 | 2017 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Selective adsorption of thiocyanate anions using straw supported ion imprinted polymer prepared by surface imprinting technique combined with RAFT polymerization
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Straw supported ion imprinted polymers for recognizing thiocyanate (SCNâ) anions were prepared by surface imprinting technique combined with reversible addition-fragmentation chain transfer (RAFT) polymerization. The ability of the imprinted straw to adsorb SCNâ ions was assessed using a batch adsorption technique. The sorption equilibrium could be reached within several minutes, and the maximum adsorption capacity was observed at pH 2.0. The imprinted straw exhibited better selectivity for SCNâ ions than the non-imprinted straw. Relative selectivity coefficients for SCNâ/CrO42â, SCNâ/NO3â and SCNâ/Iâ were 14.44, 13.97 and 14.19 respectively. The modified straw could be repeatedly used for 20 times without significant loss in the initial binding affinity. In addition, the imprinted straw was examined as a column packing material for solid phase extraction of SCNâ ions. It was indicated that 1.0 and 0.5Â mL/min were respectively the best load and elution flow rates for SCNâ ions. The relative standard deviation of the seven replicate determinations of SCNâ ions was 1.5%, and the detection limit of the proposed method was 0.42Â ng/mL. The developed method was successfully applied to the determination of trace SCNâ ions in various natural water samples with satisfactory results.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Separation and Purification Technology - Volume 177, 28 April 2017, Pages 62-70
Journal: Separation and Purification Technology - Volume 177, 28 April 2017, Pages 62-70
نویسندگان
Jingjing Wang, Yanjie Han, Juan Li, Jun Wei,