کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4995807 | 1459429 | 2017 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermal decomposition kinetics modeling of energy cane Saccharum robustum
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
جریان سیال و فرایندهای انتقال
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Three thermal decomposition stages were identified: dehydration, pyrolysis and carbonization. The activation energies were determined through three model-free methods (Friedman, Flynn-Wall-Ozawa, and Vyazovkin) varying between 107.5 and 204 kJ/mol. The master plots showed different representations of conversion functions (reaction orders from 2 to 7). The linear model fitting method validated the activation energy (177.1 kJ/mol) obtained by single-step reaction. Moreover, a multi-step method was proposed considering four independent parallel reactions (extractives, hemicellulose, cellulose, and lignin) obtaining activation energies from 60 to 181 kJ/mol, pre-exponential factor from 1.1 â 102 to 5.8 â 1012 1/s, 1st and 3rd reaction orders, and compositions from 0.12 to 0.43 with high quality of fit.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thermochimica Acta - Volume 657, 10 November 2017, Pages 56-65
Journal: Thermochimica Acta - Volume 657, 10 November 2017, Pages 56-65
نویسندگان
VinÃcius Souza de Carvalho, Katia Tannous,