|کد مقاله||کد نشریه||سال انتشار||مقاله انگلیسی||ترجمه فارسی||نسخه تمام متن|
|50113||46780||2016||3 صفحه PDF||ندارد||دانلود رایگان|
• Parameters affecting the yield and ee of hydroperoxide were studied.
• Mechanistic study was conducted to elucidate the pathway.
• Hydroperoxide was obtained by direct insertion of dioxygen into 2-oxindole.
• Byproduct was generated by preferential reduction of R-hydroperoxide.
Pentanidium catalyzed enantioselective 3-hydroperoxidation of 2-oxindoles with molecular oxygen has been established. Various 3-hydroperoxy-2-oxindoles were achieved in good ee and yield.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
Journal: Catalysis Communications - Volume 82, 5 July 2016, Pages 29–31