کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5133835 | 1492064 | 2017 | 7 صفحه PDF | دانلود رایگان |
- The viscoelasticity of O-CMC - GA coacervates was not parallel to coacervate yield.
- The properties of O-CMC and GA affected the viscoelasticity of their coacervates.
- Hydrophobic & hydrophilic interaction impacted the viscoelasticity of coacervates.
- Composition affected the viscoelasticity of the O-CMC - GA coacervate.
The effects of coacervation acidity, phase separation temperature, ionic strength, and biopolymer ratio on the viscoelasticity of the N,O-carboxymethyl chitosan (NOCC) - gum Arabic (GA) coacervate were investigated by using coacervate yield as the indicator of electrostatic interaction strength. The strongest interaction between NOCC and GA occurred at pH 3.0, whereas the highest modulus values were found in the coacervate separated at pH 6.0. The coacervate yield did not vary with phase separation temperature in the range 4-55 °C, but the coacervate viscoelasticity declined as the temperature increased from 25 °C to 45 °C and then peaked at 55 °C. The presence of NaCl weakened the electrostatic interaction between the two polyelectrolytes, but no dose-dependent reduction in viscoelasticity was observed for their coacervates. Besides, the highest electrostatic interaction strength and coacervate viscoelasticity were recorded at different GA to NOCC ratios. It is proposed that the strength of electrostatic interaction is not the only parameter that determines the viscoelasticity of the NOCC - GA coacervate.
Journal: Food Chemistry - Volume 228, 1 August 2017, Pages 236-242