Synthesis and characterization of a highly stable zinc phenylporphyrin Isoxazoline-[60] fullerene dyad: Impact of coordination on the redox and fluorescence properties

A isoxazoline-[60] fullerene derivative complex with Zn(II)-porphyrin has been first evidenced by X-Ray diffraction and characterized. The complex shows its high stability and demonstrated the coordination have clear influence on the redox behavior of the components, and the structure agrees also well with the theoretically calculated one.162