Inorganic-organic hybrid supramolecular material based on the highest connection of a Keggin arsenotungstate with electro-/photo-catalytic properties

An extraordinary supramolecular network with a (45·6)(452·638·8)(49·6)2 topology has been synthesized, which represents the highest connectivity of Keggin arsenotungstate and exhibits outstanding electrocatalytic performance for reduction of H2O2 and merit degradation behavior for MB and RhB under UV light.329