کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5356838 | 1388209 | 2018 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
PM-IRRAS studies of the adsorption and stability of organophosphonate monolayers on passivated NiTi surfaces
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Alkylphosphonic acids of different alkyl chain lengths were adsorbed on electrochemically polished NiTi surfaces from ethanolic solutions. The electropolishing process led to passive films mainly composed of Ti-oxyhydroxide. The surface showed nanoscopic etching pits with a depths of about 2Â nm and a diameter of about 20Â nm. The interfacial binding mechanism of the phosphonic acid group to the oxyhydroxide surface and the ordering of the monolayer were spectroscopically analysed by means of infrared reflection absorption FTIR-spectroscopy with (PM-IRRAS) and without (IRRAS) photoelastic modulation. The comparison of IRRAS and PM-IRRAS data of the long chain octadecylphosphonic acid monolayer proved that the binding mechanism of the phosphonic acid group to the oxyhydroxide surface is based on a mono- or bidentate bond, which is not stable in the presence of high water activities. An alkyl chain length of 17 CH2 groups is required for the formation of self-assembled monolayers, which are stable in aqueous environments. These long chain aliphatic organophosphonic acid monolayers were shown to inhibit anodic and cathodic surface reactions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 257, Issue 6, 1 January 2011, Pages 2011-2018
Journal: Applied Surface Science - Volume 257, Issue 6, 1 January 2011, Pages 2011-2018
نویسندگان
M. Maxisch, C. Ebbert, B. Torun, N. Fink, T. de los Arcos, J. Lackmann, H.J. Maier, G. Grundmeier,