کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5408147 | 1506525 | 2017 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Dissolution performance of cellulose in MIM plus tetrabutylammonium propionate solvent
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
Novel cellulose solvents, MIM-[N4444][CH3CH2COO], were developed by coupling N-methylimidazole (MIM) with tetrabutyl ammonium propionate ([N4444][CH3CH2COO]). The solubilities of cellulose in MIM-[N4444][CH3CH2COO] solvents were determined at 25 °C. The effect of MIM content on cellulose solubility and the possible dissolution mechanism of cellulose in MIM-[N4444][CH3CH2COO] solvent have been investigated. It was found that [CH3CH2COO]â anion in MIM-[N4444][CH3CH2COO] solvent is the main driving force of the cellulose dissolution by interacting with the hydroxyl hydrogen atom in cellulose, and the role of MIM is mainly to disassociate/dilute [N4444][CH3CH2COO]. In addition, the morphology and structure of the regenerated cellulose materials from MIM-[N4444][CH3CH2COO] solvent were characterized by scanning electron micrograph (SEM), Fourier transform infrared spectroscopy (ATR-FTIR) and X-ray diffraction (XRD).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 246, November 2017, Pages 153-156
Journal: Journal of Molecular Liquids - Volume 246, November 2017, Pages 153-156
نویسندگان
Ai-Rong Xu, Shuan Wen, Lin Chen,