کد مقاله کد نشریه سال انتشار مقاله انگلیسی ترجمه فارسی نسخه تمام متن
5458557 1516164 2018 8 صفحه PDF سفارش دهید دانلود کنید
عنوان انگلیسی مقاله
Effects of crystallization treatment on the structure and magnetic properties of Gd65Fe25Zn10 alloy ribbons for magnetic refrigeration
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
Effects of crystallization treatment on the structure and magnetic properties of Gd65Fe25Zn10 alloy ribbons for magnetic refrigeration
چکیده انگلیسی


- Gd65Fe25Zn10 alloys were prepared by melt-spinning followed by crystallization annealing.
- TC is close to room temperature for as-annealed Gd65Fe25Zn10 alloys.
- RC for Gd65Fe25Zn10 as-annealed alloys is higher than that of Gd5Si2Ge2 alloy.
- Large (−ΔSM)max and negligible losses make the studied alloys suitable for magnetic refrigerant.

The structure and magnetic properties of Gd65Fe25Zn10 alloy ribbons prepared by melt-spinning followed by crystallization annealing were investigated. In the as-spun ribbons, there is a small amount of α-Gd nanocrystalline existed in the amorphous matrix. After crystallization treatment, besides the pre-precipitated α-Gd phase, GdFe2 and GdZn crystalline phases precipitated in turn in the amorphous matrix. The Curie temperature (TC) of the fully amorphous matrix is ∼250 K. Owing to α-Gd nanocrystalline precipitated in the amorphous matrix, a second order magnetic transition occurs near 288 K for both the as-spun and the as-annealed Gd65Fe25Zn10 ribbons. For a field change of 2 T, the maximum magnetic entropy change (−ΔSM)max for the as-spun and as-annealed ribbons are 1.56-2.31 and 3.83-4.06 J/(kg·K), while the values of refrigeration capacity (RCFWHM) are 224.0-387.0 and 149.5-158.0 J/kg, respectively. The as-spun Gd65Fe25Zn10 ribbons display relatively low (−ΔSM)max but the largest RCFWHM value due to the wide (−ΔSM) versus T curve peak. With negligible thermal/magnetic hysteresis losses, relative large (‒ΔSM)max and its peak temperature near room temperature, the Gd65Fe25Zn10 alloy ribbons can be used as the potential magnetic refrigeration material working at room temperature.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 730, 5 January 2018, Pages 493-500
نویسندگان
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