کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5461379 | 1516199 | 2017 | 36 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A flexible mechanochemical route for the synthesis of copper oxide nanorods/nanoparticles/nanowires for supercapacitor applications: The effect of morphology on the charge storage ability
ترجمه فارسی عنوان
مسیر مکانیکی شیمیایی انعطاف پذیر برای سنتز نانوذرات / نانوذرات / نانوسیم های مس برای برنامه های کاربردی ابر کاپاسیون: تاثیر مورفولوژی بر توانایی ذخیره سازی شارژ
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
چکیده انگلیسی
A mechanochemical method has been proposed for preparing copper oxide (CuO) nanostructures with different morphologies including nanowires, nanorods and nanoparticles. The various nanostructures of CuO were synthesized by the reaction of copper (II) acetate monohydrate and diammonium oxalate monohydrate with different ratio in solvent free conditions. The obtained nanostructures were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray powder diffraction (XRD), Fourier transform infrared (FT-IR) and Brunauer-Emmett-Teller (BET) surface area analysis. It has been found that the morphology of the obtained structures can be altered by adjusting the synthesis conditions including the ball milling time and the molar ratio of the starting materials. The charge storage ability, cycle stability and ion transport of the obtained CuO nanostructures were investigated by means of cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) cycling and electrochemical impedance spectroscopy (EIS) in 6.0Â M KOH. It has been shown that the charge storage ability of the product is strongly affected by its morphology whereas the cycle stability is influenced by crystallinity. The highest specific capacitance for CuO was found to be 113.5Â FÂ gâ1 for nanoparticles at scan rate of 1Â mV/s.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 695, 25 February 2017, Pages 114-123
Journal: Journal of Alloys and Compounds - Volume 695, 25 February 2017, Pages 114-123
نویسندگان
Bahareh Ameri, Saied Saeed Hosseiny Davarani, Reza Roshani, Hamid Reza Moazami, Azadeh Tadjarodi,