River bottom sediment from the Vistula as matrix of candidate for a new reference material

- Physicochemical characteristics of natural bottom sediment from the Vistula.
- The development and validation of the method PAH extraction and determination.
- The recoveries in the range from 86% (SD=6.9) to 119% (SD=5.4) for GC/MS analysis.
- Determination analytes content and homogeneity of a new reference material.

Bottom sediments are very important in aquatic ecosystems. The sediments accumulate heavy metals and compounds belonging to the group of persistent organic pollutants. The accelerated solvent extraction (ASE) was used for extraction of 16 compounds from PAH group from bottom sediment of Vistula. For the matrix of candidate of a new reference material, moisture content, particle size, loss on ignition, pH, and total organic carbon were determined. A gas chromatograph with a selective mass detector (GC/MS) was used for the final analysis. The obtained recoveries were from 86% (SD=6.9) for anthracene to 119% (SD=5.4) for dibenzo(ah)anthracene. For the candidate for a new reference material, homogeneity and analytes content were determined using a validated method. The results are a very important part of the development and certification of a new reference materials.

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