کد مقاله کد نشریه سال انتشار مقاله انگلیسی ترجمه فارسی نسخه تمام متن
63670 1419873 2016 10 صفحه PDF سفارش دهید دانلود کنید
عنوان انگلیسی مقاله ISI
Role of nickel on vanadium poisoned FCC catalyst: A study of physiochemical properties
ترجمه فارسی عنوان
نقش نیکل بر روی کاتالیزور FCC مسموم وانادیوم: مطالعه خواص فیزیکی
کلمات کلیدی
کاتالیزور FCC. فلزات آلاینده؛ فعالیت؛ خواص فیزیکوشیمیایی؛ مکانیزم
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
چکیده انگلیسی

Active sites of Fluid catalytic cracking (FCC) catalyst are poisoned during operation in the FCC reactor due to causes including feedstock contaminant metals deposition. This leads to activity, selectivity and increasing coking problems, thereby raising concern to the refiner. This work investigated effect of nickel coexisting with vanadium in the FCC feedstock on the standard FCC catalyst during cracking process, in which destruction of active sites occurs as a result of the metals deposition. Laboratory simulated equilibrium catalysts (E-cats) were studied by XRD, FTIR spectroscopy, N2 adsorption, solid state MAS-NMR, SEM and H2-TPR. Results revealed that vanadium, above a certain concentration in the catalyst, under hydrothermal conditions, is highly detrimental to the catalyst's structure and activity. Conversely, nickel hardly affects the catalyst structure, but its co-presence in the catalyst reduces destructive effects of vanadium. The mechanism of nickel inhibition of vanadium poisoning of the catalyst is discussed.

Vanadium degrades crystallinity of the catalyst when it exists alone, but in the presence of nickel, another catalyst poison, crystallinity is retained. This behavior follows reactions between the metals according to the equations in the picture. Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Energy Chemistry - Volume 25, Issue 4, July 2016, Pages 667–676
نویسندگان
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