کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6470153 | 1424104 | 2017 | 8 صفحه PDF | دانلود رایگان |
- Nonstoichiometric of mesoporous LaMn1±xO3 perovskite can be easily synthesized by sol-gel.
- Oxygen vacancies and Mn4+ ions concentrations can be modulated by Mn/La ratio.
- A high specific capacity of 202.1 mAhgâ1 (727.6 Cgâ1) is obtained for LaMn1.1O3-δ.
A series of LaMn1±xO3 perovskite (x = 0, 0.05, 0.1) has been synthesized via a facile sol-gel method and applied as supercapacitor electrodes. The morphology, phase structure, composition, chemical states of constituents and electrochemical properties are investigated. As a result, all the LaMn1±xO3 samples revealed a single mesoporous phase of perovskite with typical pore sizes from 2 to 5 nm. The nonstoichiometric LaMn1.1O3 sample showed much higher specific capacity (202.1 mAhgâ1/727.6 Cgâ1 at 1 Agâ1) than stoichiometric LaMnO3 perovskite (114.4 mAhgâ1/411.8 Cgâ1 at 1 Agâ1). Detailed chemical analysis demonstrated that the presence of point defects such as oxygen and cation vacancies, and a high Mn4+/Mn3+ ratio contributed to the excellent electrochemical performance. Furthermore, the cycle stability analyses of the LaMn1±xO3 perovskite revealed that LaMn1.1O3 manifested an exceptionally high rate capability. These results prove that nonstoichiometric LaMn1.1O3 can be a promising material for supercapacitor electrodes.
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Journal: Electrochimica Acta - Volume 253, 1 November 2017, Pages 422-429