کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6472300 | 1424137 | 2016 | 5 صفحه PDF | دانلود رایگان |
- LiFePO4 has been synthesized by a facile hydrothermal method using iron metal directly as an iron source.
- Theoretically iron metal delivers 100% atom economy.
- The LiFePO4 electrode demonstrates good electrochemical performance.
Hydrothermal LiFePO4 has been successfully synthesized using iron powder as an iron source and as an in situ reducing agent. The 100% atom economy delivered by iron metal (Fe0) makes this process green and inexpensive. A plausible mechanism for the formation of hydrothermal LiFePO4 powder is also proposed. The structure of the LiFePO4 powder is well characterized by X-ray diffraction, scanning electron microscopy and transmission electron microscopy techniques. The discharge capacity of the LiFePO4 electrode is found to be 165 mAh gâ1 at 0.1 C-rate, and the cycle-life performance is comparable to the conventionally synthesized LiFePO4.
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Journal: Electrochimica Acta - Volume 220, 1 December 2016, Pages 164-168