کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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6472531 | 1424135 | 2016 | 9 صفحه PDF | دانلود رایگان |
We report a fabrication of nano-flakes consisting of Ni-Al layered double hydroxide grown on functionalized carbon nanotube bundles by a hydrothermal method for energy storage application. This nano-flake structure is denoted as Ni-Al LDH/CNTs. The morphology characterization indicates that the composite displays a three-dimensional architecture with a well-defined core-shell configuration and large surface area. Due to its unique core-shell structure, the Ni-Al LDH/CNTs electrode with a mass loading of 50Â mg/cm2 reaches a high electrochemical performance of 1017C/g (the corresponding area-normalized capacity is 50.85C/cm2) at a current density of 1Â A/g, and excellent rate performance (remains 85% when the current density increases to 10Â A/g). Furthermore, the composite exhibits good behavior during life testing with a decrease of the specific capacity of 88% after 1000 cycle tests at a current density of 2Â A/g, indicating the composite has adequate high-current electrochemical behavior. The attractive electrochemical performance of this Ni-Al LDH/CNTs illustrates its unique advantage for energy storage systems. In addition, the rational design demonstrated here a blueprint for a cheap synthesis of a CNTs-based three-dimensional nano core-shell structure.
Journal: Electrochimica Acta - Volume 222, 20 December 2016, Pages 185-193