Keywords: بیش از حد انعطافی; CuAAC; Copper-Catalyzed Azide-Alkyne Cycloadditions; PhSH; thiophenol; alloc; allylcarbamate group; DAPI; 4â²,6-diamidine-2â²-phenylindole; EtBr; ethidium bromide; TON; turnover number; GSH; glutathione; PBS; phosphate buffered saline; TPP; triphenylp
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Keywords: بیش از حد انعطافی; Acac; acetylacetone; Ar; aryl; BDPP; 2,4-bis(diphenylphosphino)pentane; BINAP; 2,2â²-bis(diphenylphosphino)-1,1â²-binaphthyl; BINOL; 1,1â²-bi-2-naphthol; Bn; benzyl; Boc; tert-butoxycarbonyl; Bz; benzoyl; Cbz; benzyloxycarbonyl; Cy; cyclohexyl; DCE; 1,
Keywords: بیش از حد انعطافی; Ac; acetyl; AD-mix; asymmetric dihydroxylation mix; ATP; adenosine triphosphate; Bn; benzyl; Boc; tert-butyloxycarbonyl; Bu; butyl (n-Bu, n-butyl; I; isobutyl; sec-Bu; sec-butyl; t-Bu; tert-butyl); Bz; benzoyl; CAL-B; Candida antartcia lipase-B; CAN; ceri
Quantitative chiral analysis of amino acids in solution using enantiomer-selective photodissociation of cold gas-phase tryptophan via chiral recognition
Keywords: بیش از حد انعطافی; Enantiomeric excess; Mass spectrometry; Electrospray ionization; Chemical evolution; Homochirality;
Keywords: بیش از حد انعطافی; Ac; acetyl; An; anisyl; Ar; aryl; ATP; adenosine triphosphate; Bn; benzyl; Boc; tert-butoxycarbonyl; Bu; butyl; Bz; benzoyl; cat; catalyst; conv; conversion; Cy; cyclohexyl; DABCO; 1,4-diazabicyclo[2.2.2]octane; DBU; 1,8-diazabicyclo[5.4.0]undec-7-ene; de
Vanadium complexes supported on organic polymers as sustainable systems for catalytic oxidations
Keywords: بیش از حد انعطافی; PS; polystyrene cross-linked with divinyl benzene; PS-CH2-Cl; chloromethylated PS; PS-im; imidazolomethylpolystyrene; PEG; polyethyleneglycol; acac; acetylacetonato; PMAn; cross linked polyacrylate polymers; c-PMAn-V; polymer anchored vanadium compounds o
Recent developments in enantioselective lanthanide-catalyzed transformations
Keywords: بیش از حد انعطافی; Ar; aryl; BINOL; 1,1â²-bi-2-naphthol; Bpy; 2,2â²-bipyridyl; Bn; benzyl; BNP; Binaphthophosphole; Boc; tert-butoxycarbonyl; BSA; bis-(trimethylsilyl)acetamide; CB; carbon black; cod; 1,5-cyclooctadiene; Cy; cyclohexyl; DBDMH; 1,3-dibromo-5,5-dimethylhyda
Keywords: بیش از حد انعطافی; AFM; atomic force microscopy; BET; Brunauer-Emmett-Teller; BINAP; (2,2â²-bis(diphenylphosphino)-1,1â²-binaphthyl); CB; carbon black; CDC; cross-dehydrogenative coupling; CN-DSCS; copper nanoparticle-doped silica cuprous sulfate; CNS; central nervous
Catalyst recycling-A survey of recent progress and current status
Keywords: بیش از حد انعطافی; AAS; atomic absorption spectroscopy; AB; ammonia-borane (H3N:BH3); acac; acetylacetonate; BAIB; [bis(acetoxy)iodo]benzene; bdmi; 1-butyl-2,3-dimethylimidazolium; BARF; tetrakis-[3,5-bis(trifluoromethyl)phenyl]borate; BINAM; 1,1â²-binaphthyl-2,2â²-diam
Rational design of metalloenzymes: From single to multiple active sites
Keywords: بیش از حد انعطافی; UAAs; unnatural amino acids; Rd; rubredoxin; EPR; electron paramagnetic resonance; Az; azurin; SOR; superoxide reductase; PDB; protein data bank; 6-PGLac; 6-phosphogluconolactonase; H-bond; hydrogen-bond; NIR; nitrite reductase; ET; electron transfer; 3SC
Keywords: بیش از حد انعطافی; Nitro compounds; Natural products; Pharmaceuticals; Stereoselective synthesis; Organocatalysis; Metal catalysis; Nitronates; Nitrile oxides; AIBN; azobisisobutyronitrile; AZADO; 2-azaadamantane-N-oxyl; 9-BBN; 9-borabicyclo[3.3.1]nonane; BINAP; 2,2â²-bis(
Keywords: بیش از حد انعطافی; Ac; acetyl; acac; acetylacetonate; AHPCS; allylhydridopolycarbosilane; Bn; benzyl; Boc; tert-butoxycarbonyl; BPR; back pressure regulator; bpy; 2,2â²-bipyridine; Bu; butyl; CFL; compact fluorescent lamp; DCB; 1,4-dicyanobenzene; de; diastereomeric excess
Keywords: بیش از حد انعطافی; Enantiomeric excess; Chiral selector; Capillary electrophoresis; Velocity gap mode;
Keywords: بیش از حد انعطافی; ee; enantiomeric excess; CesA; carboxylesterase CesA; CesB; carboxylesterase CesB; MCP; meta-cleavage compound; IPG; 1,2-O-isopropylideneglycerol; NP; carboxylesterase NP; α/β Hydrolase; Carboxylesterase; MCP hydrolase; Molecular modeling; X-ray crystal
Keywords: بیش از حد انعطافی; ACN; acetonitrile; AFM; atomic force microscopy; AIBN; 2,2â²-azobis-isobutyronitrile; APS; ammonium persulfate; AM; acrylamide; AML; amlodipine; ATRP; atom-transfer radical polymerization; BMA; butyl methacrylate; Boc; tert-butoxycarbonyl; Boc-Trp; tert-
Keywords: بیش از حد انعطافی; Ephedrinium salts; Morita-Baylis-Hillman reaction; Asymmetric induction; Enantiomeric excess; Micellar micro-environment
Enantioselective synthesis of (R)-phenylephrine by Serratia marcescens BCRC10948 cells that homologously express SM_SDR
Keywords: بیش از حد انعطافی; E. coli; Escherichia coli; HPLC; high performance liquid chromatography; HPMAE; 1-(3-hydroxyphenyl)-2-(methylamino) ethanone; PDE; pseudoephedrine; PE; phenylephrine; S. marcescens; Serratia marcescens; SDR; short-chain dehydrogenase/reductase; SM_SDR; S.
Simultaneous biosynthesis of (R)-acetoin and ethylene glycol from D-xylose through in vitro metabolic engineering
Keywords: بیش از حد انعطافی; EG; ethylene glycol; PET; polyethylene terephthalate; ThDP; Thiamine diphosphate; FAD; flavin adenine dinucleotide; NAD+; oxidized nicotinamide adenine dinucleotide; NADH; reduced nicotinamide adenine dinucleotide; LB; lysogeny broth; IPTG; isopropyl-β-D
Synthesis of MOFs for heterogeneous catalysis via linker design
Keywords: بیش از حد انعطافی; MOFs; metal-organic frameworks; PCNs; porous coordination networks; PCPs; porous coordination polymers; PSM; post-synthetic modifications; SBUs; secondary building units; TCPP; tetrakis(4-carboxyphenyl)porphyrin); MMPF; metal-metalloporphyrin framework;
Synthesis, characterization and applications of some novel DMAP-based chiral ionic liquids
Keywords: بیش از حد انعطافی; Chiral ionic liquids; Asymmetric reduction; Enantiomeric excess; Chirality; Chiral recognition;
Optimization of a two-dimensional liquid chromatography-supercritical fluid chromatography-mass spectrometry (2D-LC-SFS-MS) system to assess “in-vivo” inter-conversion of chiral drug molecules
Keywords: بیش از حد انعطافی; Liquid chromatography; Supercritical fluid chromatography; Active pharmaceutical ingredients; Metabolites; Enantiomeric excess; 2D LC-SFC-MS;
Enantiomeric ratios: Why so many notations?
Keywords: بیش از حد انعطافی; Chirality; Enantiomers; Enantiomeric fraction; Enantiomeric ratio; Enantiomeric excess;
Impact of chirality on the Glass Forming Ability and the crystallization from the amorphous state of 5-ethyl-5-methylhydantoin, a chiral poor glass former
Keywords: بیش از حد انعطافی; 5-Ethyl-5-methylhydantoin (PubChem CID: 82,162); API; Active Pharmaceutical Ingredient; GFA; Glass Forming Ability; FSC; Fast Scanning Calorimetry; DSC; Differential Scanning Calorimetry; BCS; BioPharmaceutical Classification System; ee; Enantiomeric Exce
Determination of enantiomeric excess of some amino acids by second-order calibration of kinetic-fluorescence data
Keywords: بیش از حد انعطافی; Fluorimetric detection; Enantiomeric excess; Chemometrics; Amino acids; o-phthaldialdehyde;
Enantioselective hydrolysis of ibuprofen ethyl ester by a thermophilic immobilized lipase, ELT, from Rhodothermus marinus
Keywords: بیش از حد انعطافی; R. marinus; Rhodothermus marinus; ELT; Esterase/lipase/thioesterase; E-value; Enantiomeric value; ee; Enantiomeric excess; CS-MNPs; Chitosan coated Fe3O4-nanparticles; EDC; N-ethyl-Nʹ-(3-(dimethylamino)propyl) carbodiimide hydrochloride; Biotransformatio
d-Amino acids in molecular evolution in space - Absolute asymmetric photolysis and synthesis of amino acids by circularly polarized light
Keywords: بیش از حد انعطافی; Ala; alanine; Glu; glutamic acid; Met; methionine; Leu; leucine; Tyr; tyrosine; Phe; phenylalanine; Asp; aspartic acid; Ser; serine; Arg; arginine; His; histidine; Pro; proline; Asn; asparagine; NVal; norvaline; NLeu; norleucine; Ile; isoleucine; ABA; ami
Enantiomeric quantification of amines by 1H and 13C NMR: First report of S-citronellal as chiral derivatization agent (CDA)
Keywords: بیش از حد انعطافی; S-citronellal; Amine; NMR; CDA; Quantification; Enantiomeric excess;
Chiral resolution of serial potent and selective Ï1 ligands and biological evaluation of (â)-[18F]TZ3108 in rodent and the nonhuman primate brain
Keywords: بیش از حد انعطافی; calcd; calculated; CH2Cl2; dichloromethane; CNS; central nervous system; DMSO; dimethyl sulfoxide; [3H]DTG; [3H]ditolylguanidine; DTTA; di-p-toluoyl tartaric acid; EBP; emopamil binding protein; ee; enantiomeric excess; EOB; end of bombardment; EtOH; etha
Recent advances in asymmetric multicomponent reactions (AMCRs)
Keywords: بیش از حد انعطافی; AMCRs; asymmetric multicomponent reactions; BINOL; 1,1â²-bi-2-naphthol; DCE; dichloroethane; de; diastereomeric excess; DIPEA; diisopropylethylamine; DMCHA; dimethylcyclohexylamine; dppe; (diphenylphosphino)ethane; d.r.; diastereomeric ratio; ee; enantio
Biosynthesis-inspired deracemizative production of d-luciferin by combining luciferase and thioesterase
Keywords: بیش از حد انعطافی; AMACR; α-methyl-acyl-CoA-racemase; CHBT; 2-cyano-6-hydroxybenzothiazole; CoASH; Coenzyme A; ee; enantiomeric excess; DMEM; Dulbecco's Modified Eagle Medium; E-luc; luciferase from Pyrearinus termitilluminans; LUC-G; firefly luciferase from Luciola crucia
Enantioselective synthesis of axially chiral 3-bromo-4-alkoxy-2,6-dimethyl-5-(naphthalen-1-yl)pyridines via an asymmetric Suzuki-Miyaura cross-coupling reaction
Keywords: بیش از حد انعطافی; Atropisomer; Asymmetric synthesis; Enantiomeric excess; Palladium-catalyzed reaction; Chiral ligand;
Biosynthesis of optically pure chiral alcohols by a substrate coupled and biphasic system with a short-chain dehydrogenase from Streptomyces griseus
Keywords: بیش از حد انعطافی; SDRs; short-chain dehydrogenases/reductases superfamily; CR; carbonyl reductase; SgCR; carbonyl reductase from Streptomyces griseus; COBE; ethyl 4-chloro-3-oxobutanoate; (S)-CHBE; (S)-4-chloro-3-hydroxybutanoate; IPT; gisopropyl β-d-1-thiogalactopy-ranos
Tetrahedron report 1111Synthesis routes to anti-HIV drugs
Keywords: بیش از حد انعطافی; AIDS; Anti-HIV; Synthesis; FDA; Enantiomeric excess; ABC; abacavir; AIBN; azobisisobutyronitrile; AIDS; acquired immune deficiency syndrome; ARV; antiretroviral; AZT; 3â²-azido-3â²-deoxythymidine; CAPIC; 2-chloro-3-amino-4-picoline; CD4; cluster of diff
Scalemic and racemic imprinting with a chiral crosslinker
Keywords: بیش از حد انعطافی; Molecular imprinting; Chiral crosslinker; Chiral selectivity; Enantiomeric excess; Scalemic/racemic templates; Chiral stationary phase;
In vitro and in vivo toxicological studies of V nerve agents: Molecular and stereoselective aspects
Keywords: بیش از حد انعطافی; GA; tabun; GB; sarin; GD; soman; GF; cyclosarin; VX; O-ethyl S-[2-(diisopropylamino)ethyl] methylphosphonothiate; VR; O-isobutyl S-[2-(diethylamino)ethyl] methylphosphonothiate; EA-2192; S-[2(diisopropylamino)ethyl] methylphosphonothioic acid; OP; organop
Stereoselective synthesis of 3-hydroxy-3-methylglutaryl-coenzyme A reductase inhibitors
Keywords: بیش از حد انعطافی; HMG-CoA reductase inhibitors; Statins; Chiral β-hydroxy-δ-lactone; Chiral 3,5-syn-diol acid; Asymmetric synthesis; Ac; acetyl; Ar; aryl; Bn; benzyl; Bz; benzoyl; n-Bu; butyl; t-Bu; tert-butyl; CDI; 1,1â²-carbonyldiimidazole; BINOL; 1,1â²-bi-2-naphthol
An update on the stereoselective synthesis of α-aminophosphonic acids and derivatives
Keywords: بیش از حد انعطافی; α-Aminophosphonic acids; α-Aminophosphonates; Stereoselective synthesis; Three-component reaction; ABSA; 4-acetamidobenzenesulfonyl azide; Abu; aminobutyric acid; Ac; acetyl; ACE; angiotensin-converting enzyme; Ala; alanine; Ar; aryl; BINAP; 2,2â²-bis(
Chemical synthesis of tetracyclic terpenes and evaluation of antagonistic activity on endothelin-A receptors and voltage-gated calcium channels
Keywords: بیش از حد انعطافی; 2D NOESY; two-dimensional nuclear Overhauser effect spectroscopy; Dibal-H; diisobutylaluminum hydride; DRG; dorsal root ganglion; ee; enantiomeric excess; ET-1; endothelin-1; ETA; endothelin A receptors; EGTA; ethylene glycol tetraacetic acid; EC50; media
Improved enantioseparation via the twin-column based recycling high performance liquid chromatography
Keywords: بیش از حد انعطافی; Enantioseparation; Recycling HPLC; Chiral HPLC; Enantiomeric excess; Isoxazolidines; Twin-column based
Quantification of the enantiomeric excess of two APIs by means of near infrared spectroscopy and chemometrics
Keywords: بیش از حد انعطافی; Enantiomeric excess; Near infrared spectroscopy (NIR); Ibuprofen; Epinephrine; Partial least squares (PLS) regression
Enantioseparations of amino acids by capillary array electrophoresis with 532 nm laser induced fluorescence detection
Keywords: بیش از حد انعطافی; Capillary array electrophoresis; Chiral amino acids; Cyclodextrins; Enantiomeric excess; Rhodamine-core fluorescent probe
Stereochemical characterization of fluorinated 2-(phenanthren-1-yl)propionic acids by enantioselective high performance liquid chromatography analysis and electronic circular dichroism detection
Keywords: بیش از حد انعطافی; Enantioselective HPLC; Circular dichroism detection; Absolute configuration; Enantiomeric excess
On-line chiral analysis of benzylmercapturic acid and phenylmercapturic acid in human urine using UPLC-QToF mass spectrometry with the kinetic method
Keywords: بیش از حد انعطافی; Chiral analysis; d/l-Phenylmercapturic acid; d/l-Benzylmercapturic acid; Enantiomeric excess; Kinetic method;
Further insight in the minor/major concept using hydrogen pressure effect in asymmetric hydrogenation
Keywords: بیش از حد انعطافی; Asymmetric hydrogenation; Hydrogen pressure; Enantiomeric excess; (R,R)-Me-BPE; M-acrylate; E-emap
Alkaloid induced asymmetric electrocarboxylation of 4-methylpropiophenone
Keywords: بیش از حد انعطافی; Cinchonine; Induction; Electrocarboxylation; Enantiomeric excess; Carbon dioxide;
Site-directed mutagenesis of epoxide hydrolase to probe catalytic amino acid residues and reaction mechanism
Keywords: بیش از حد انعطافی; EH; epoxide hydrolase; HAD; haloacid dehalogenase; EE; enantiomeric excess; SDS-PAGE; sodium dodecyl sulfate-polyacrylamide gel electrophoresis; Hdl; L-2-haloacid dehalogenase IVa from Pseudomonas cepacia MBA4; DehCI; L-2-haloacid dehalogenase I from
Synthesis of C2-symmetric chiral crown ethers by lipase-catalyzed reactions
Keywords: بیش از حد انعطافی; Chiral crown ethers; Lipase-catalyzed reaction; Enantiomeric excess; Absolute configuration;
Recent developments in dynamic kinetic resolution
Keywords: بیش از حد انعطافی; Ac; acetyl; AIBN; 2,2â²-azobisisobutyronitrile; Ar; aryl; Atm; atmosphere; BARF; tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; BINAP; 2,2â²-bis(diphenylphosphanyl)-1,1â²-binaphthyl; BINOL; 1,1â²-bi-2-naphthol; BIPHEP; 2,2â²-bis(diphenylphosphino)-1
Selective detection of single-enantiomer spectrum of chiral molecules aligned in the polypeptide liquid crystalline solvent: Transition selective one-dimensional 1H-1H COSY
Keywords: بیش از حد انعطافی; Transition selective excitation; Residual dipolar couplings; Enantiomeric excess; Enantiopure spectrum; Spectral simplification; Correlated spectroscopy;
Quantum molecular interaction field models of substrate enantioselection in asymmetric processes
Keywords: بیش از حد انعطافی; QSAR; Asymmetric catalysis; Enantiomeric excess; Quantum molecular interaction fields; Mechanism