Synthesis and magnetic behavior of prussian blue analogues Mn3[Fe(CN)6]2·12H2O porous nanoparticles

Mn3[Fe(CN)6]2·12H2O nanoparticles with different sizes, charge distribution and morphologies by controlling the reaction solvent, which lead to the different magnetic behaviors. Although magnetic measurements show that Mn3[Fe(CN)6]2·12H2O nanocubes (about 480 nm) and nanospheres (about 200 nm) both have ferrimagnetic and spin-glass behaviors, their freezing temperature and Tc are obvious difference.244