Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10141597 | Journal of Molecular Liquids | 2018 | 8 Pages |
Abstract
The equilibrium solubility of triclocarban in {1,4-dioxane (1)â¯+â¯water (2)} mixtures at 293.15â¯K to 313.15â¯K was reported. Mole fraction solubility increases continuously from neat water to neat 1,4-dioxane at all temperatures. Solubility behavior was adequately correlated by means of a number of cosolvency models including the Jouyban-Acree model. Based on the Gibbs and van't Hoff equations the respective apparent thermodynamic quantities of dissolution were calculated. Non-linear enthalpy-entropy compensation analysis is observed indicating different dissolution mechanism with the variation in mixtures composition.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Daniel R. Delgado, Edgar M. Mogollon-Waltero, Claudia P. Ortiz, MarÃa Á. Peña, Ovidio A. Almanza, Fleming MartÃnez, Abolghasem Jouyban,