Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10145360 | Electrochimica Acta | 2018 | 35 Pages |
Abstract
This article sheds light on advantages of fast charging methods with time-varying current. Analytical solutions of concentration and stress for charging processes with general time-varying currents are derived. A fast charging protocol for a multistage constant current of gradually decreasing value is first evaluated. A properly designed multistage constant-current method is able to simultaneously suppress stress overflow and accelerate charging, but stress undulation induced by sharp switching between stages is inevitable. A charging scheme with a nonlinear exponential current is then investigated. The applied current varies continuously and smoothly with time so stress undulation is avoided. Suggestions for the design of an exponential current method are proposed to achieve the best charging acceleration without sacrificing charging capacity or increasing risk of mechanical failures. A well-designed exponential-current method is superior to a multistage constant-current method in accelerating charging speed.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Bo Lu, Yanfei Zhao, Yicheng Song, Junqian Zhang,