Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10155449 | Ceramics International | 2018 | 18 Pages |
Abstract
Cr-doped Ba2In2-xCrxO5+y (0â¯â¤â¯xâ¯â¤â¯0.5) orange-brown inorganic oxides have been successfully synthesized by solid-state reaction. X-ray diffraction (XRD) patterns show that their crystal structures transform from orthorhombic to cubic by increasing the Cr doping amount. Field emission scanning electron microscopy (FESEM) measurements show powder particles of irregular shape with average particle size of about 10â¯Âµm. The colors of the compounds are tuned from light yellow (xâ¯=â¯0) to orange (xâ¯=â¯0.1) and then to dark brown (xâ¯=â¯0.5). X-ray photoelectron spectroscopy and UV-Vis absorption spectroscopy demonstrate the oxidation state of Cr to be +â¯6 and the change in color to be due to the metal-ligand charge transfer of Cr6+-O2-.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Honghong Lei, Yuncheng Zhou, Peng Jiang, Wei Wang, Wenbin Cao, Yawen Xue,