Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10155491 | Journal of the European Ceramic Society | 2018 | 34 Pages |
Abstract
A series of ceramic samples were prepared and characterized at 1400â°C in the BaO-TiO2-YO1.5 system. The obtained experimental results were adopted to the present thermodynamic evaluation to derive a set of thermodynamic database for the BaO-TiO2-YO1.5 system. The database was constructed by the CALPHAD method where the binary parameters from BaO-TiO2 and TiO2-YO1.5 systems were re-optimized, those from the BaO-YO1.5 system were simulated by our previous assessments. Thermodynamics descriptions of all liquid and terminal solid solution phases were treated by the substitutional solution model, the H-BaTiO3 (BaTiO3, hexagonal structure) and C-BaTiO3 (BaTiO3, cubic structure) were described by the compound energy formalism model, and other binary intermediate phases were treated as the stoichiometric compounds. Finally, some thermodynamic diagrams were calculated and compared with the experimental results. Good agreement between present calculations and the experimental results demonstrates that the present thermodynamic database is self-consistent and credible.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Xiaomei Liu, Zhu Li, Jing Wang, Rulin Zhang, Wajid Ali, Shihua Wang, Xionggang Lu, Chonghe Li,