Article ID Journal Published Year Pages File Type
10156043 Materials Letters 2019 15 Pages PDF
Abstract
Ag2S hollow nanospheres were synthesized by reaction between silver dodecanoate and thiourea in the presence of polyvinyl pyrrolidone (PVP) at ambient temperature within 30 min. Characterization studies by X-ray powder diffraction (XRD), energy dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM) and scanning electron microscopy (SEM) showed that the prepared product had a monoclinic structure and was composed of thin shell enwrapped hollow nanospheres. Their large band gap energy of 3.67 eV, remarkable blue shifts both in the ultraviolet-visible (UV-vis) absorption spectrum and the photoluminescence (PL) emission peak could be well explained by the thin shell caused quantum confinement effects.
Related Topics
Physical Sciences and Engineering Materials Science Nanotechnology
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