Article ID Journal Published Year Pages File Type
10225162 Dyes and Pigments 2019 48 Pages PDF
Abstract
A series of β-functionalized D-A porphyrins have been synthesized via Suzuki coupling reaction. Synthesized free base porphyrins exhibited very high protonation constants (logβ2 = 9.59-10.45). An efficient Förster resonance through bond energy transfer (78-88%) from β-substituents to macrocyclic core was supported by steady state and time resolved fluorescence measurements. Free base β-trisubstituted porphyrins exhibited highest protonation constants so far known in the literature.329
Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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