Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10225162 | Dyes and Pigments | 2019 | 48 Pages |
Abstract
A series of β-functionalized D-A porphyrins have been synthesized via Suzuki coupling reaction. Synthesized free base porphyrins exhibited very high protonation constants (logβ2â¯=â¯9.59-10.45). An efficient Förster resonance through bond energy transfer (78-88%) from β-substituents to macrocyclic core was supported by steady state and time resolved fluorescence measurements. Free base β-trisubstituted porphyrins exhibited highest protonation constants so far known in the literature.329
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Nitika Grover, Nivedita Chaudhri, Muniappan Sankar,