Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10239002 | Applied Catalysis A: General | 2005 | 10 Pages |
Abstract
The kinetics and mechanism of the reduction of NO and N2O by H2 over Ag/Al2O3 were studied with transient step response and isotope exchange techniques. Dissociation of hydrogen and deuterium was observed on the Ag/alumina catalyst. The reduction of NO with hydrogen gave N2 as the main product and N2O, NH3 and H2O as by-products, while the catalyst showed low activity for the self-decomposition of NO and N2O. To clarify the reaction mechanism for the reduction of NO with hydrogen parameter estimation and modeling was carried out.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Henrik Backman, Jenny Jensén, Fredrik Klingstedt, Tapio Salmi, Dmitry Yu. Murzin,