Article ID Journal Published Year Pages File Type
10239002 Applied Catalysis A: General 2005 10 Pages PDF
Abstract
The kinetics and mechanism of the reduction of NO and N2O by H2 over Ag/Al2O3 were studied with transient step response and isotope exchange techniques. Dissociation of hydrogen and deuterium was observed on the Ag/alumina catalyst. The reduction of NO with hydrogen gave N2 as the main product and N2O, NH3 and H2O as by-products, while the catalyst showed low activity for the self-decomposition of NO and N2O. To clarify the reaction mechanism for the reduction of NO with hydrogen parameter estimation and modeling was carried out.
Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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